No, it is not possible. Once you click Upgrade Now at any of the site collections, it will automatically trigger the upgrade process for all of them.
You may test the sites using the Sandbox Mode before upgrading.
To check the new design elements and connections you will be able to edit page, test them and preview using the Preview button for those elements or sections. Using the Sandbox Mode you will also be able to check if there are new features in Theme Builder.
Tip: If you need to check more sites in Sandbox Mode before upgrading, do not close the Sandbox Mode just yet. Upgrading from any of the sites will close the Sandbox Mode from all of them.
Please note that you cannot save the changes: insert or update the elements and republish Theme Builder customizations.
Also, you might have the test environments for such purpose and check the new version there.
Alternatively, you may preview any of the versions starting from ShortPoint SPFx 7.1.5.xx, using the query string at the end of your URL. Please, check this solution article for more details: Preview Any ShortPoint SPFx Version on a Page Using a URL Parameter.